引用本文:尹燕敏,顾海东,秦宏兵.超高效液相色谱三重四极杆质谱联用法测定水中的丙烯酰胺[J].环境监控与预警,2012,4(6):20-22
.Determination of Acrylamide in Drinking Water by Ultra Performance Liquid Chromatography Coupled with Triple Quadrupole Mass Spectrometry[J].Environmental Monitoring and Forewarning,2012,4(6):20-22
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超高效液相色谱三重四极杆质谱联用法测定水中的丙烯酰胺
尹燕敏,顾海东,秦宏兵
苏州市环境监测中心站,江苏 苏州 215004
摘要:
将含有丙烯酰胺的水样过滤后加入甲酸酸化,然后直接进样,使用超高效液相色谱三重四极杆质谱联用法测定,通过选择离子反应监测,可实现定性和外标法定量分析。该方法测定生活饮用水及其水源水中丙烯酰胺的最低检测浓度为0.15 mg/L,对实际样品的加标回收率在92 %~123 %,该方法绿色环保、简单方便,且具有较高的灵敏度和较低的检出限。
关键词:  丙烯酰胺  超高效液相色谱三重四极杆质谱联用仪  直接测定
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Determination of Acrylamide in Drinking Water by Ultra Performance Liquid Chromatography Coupled with Triple Quadrupole Mass Spectrometry
Abstract:
Water samples containing acrylamide were filtered and acidized by formic acid, then directly injected and finally detected by ultra performance liquid chromatography coupled with triple quadrupole mass spectrometry. Qualitative and quantitative analysis by external standard were achieved by electrospray ionization in positive mode using multiple reaction monitoring. The limit of determination for acrylamide in drinking water was 0.15mg/L. The average recovery rate of real samples was in the range of 92%~123%. This method was environment friendly, simple and sensitive.
Key words:  acrylamide  ultra performance liquid chromatography coupled with triple Quadrupole mass spectrometry  directly determination