| 摘要: |
| 分别用原子荧光法（AFS）和电感耦合等离子体质谱法（ICP-MS）测定水中锑。AFS法和ICP-MS法均线性良好，相关系数分别为0.9998和0.9999，检出限分别为0.17和0.03μg/L，〖JP3〗相对标准偏差均＜1.15%，加标回收率分别为96.6%~111.9%和95.4%~111.5%，2种方法均能很好地用于水中锑的测定。其中，ICP-MS法适合较清洁地表水和地下水样品中锑的分析，AFS法则对地表水、地下水和废水样品均适用。 |
| 关键词: 原子荧光法 电感耦合等离子体质谱法 锑 水 |
| DOI： |
| 分类号:X832；O657.31；O651.6 |
| 文献标识码:B |
| 基金项目:国家水体污染控制与治理科技重大专项资助项目（2012ZX07506—003） |
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| Comparison between AFS and ICP MS in the Determination of Antimony in Water |
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ZHANG Xiaoyun，GU Xiaoming，ZHOU Minfeng，QIN Hongbing
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Suzhou Environmental Monitoring Center，Suzhou，Jiangsu 215000，China
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| Abstract: |
| Antimony in water was determined by AFS and ICP MS methods. The linearity was good for antimony determined both by AFS and ICP MS，with correlation coefficients 0.999 8 and 0.999 9，respectively. The limits of detection were 0.17 and 0.03μg/L， respectively. The RSDs of both methods were less than 1.15%， The recoveries were in the range of 96.6 %~111.9%， and 95.4%~111.5% for AFS and ICP MS， respectively.Both of the two methods can be used to determine antimony in water samples effectively. ICP-MS was better for the determination of antimony in cleaner surface water and groundwater， while AFS was more suitable for surface water， groundwater and waste water. |
| Key words: AFS ICP MS Antimony Water |
