引用本文:董军,袁鹏辉,马超,高帅,王青华,范晓静.固相萃取-气相色谱/质谱法测定地下水中15种农药残留[J].环境监控与预警,2017,9(1):28-31
DONG Jun,YUAN Peng hui,MA Chao,GAO Shuai,WANG Qing hua,FAN Xiao jing.SPE-GC/MS Method for the Determination of 15 Pesticide Residues in Ground Water[J].Environmental Monitoring and Forewarning,2017,9(1):28-31
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固相萃取-气相色谱/质谱法测定地下水中15种农药残留
董军,袁鹏辉,马超,高帅,王青华,范晓静1,2
1. 山东省地矿工程勘察院,山东 济南 250014;2. 中国石油大学(北京)重质油国家重点实验室,北京 102249
摘要:
通过优选色谱柱,进一步改进色谱分离条件,优化前处理方法,建立一种快速高效测定地下水中15种农药残留量的GC-MS方法。该法采用分段法选择离子(SIM)扫描,具有更高的灵敏度、较低的检出限和较高的回收率,检出限低于0.004 8 μg/L,回收率为85.9%~107.4%。本方法的突出特点是前处理速度快、萃取溶剂用量少、环境污染小、色谱运行时间短,基本稳定在25 min内完成分析,适用于大批量样品检测。
关键词:  地下水  农药  GC-MS
DOI:
分类号:X832; O657.6; O657.7
文献标识码:B
基金项目:山东省2015年度31个省级地质勘查基金资助项目(SDZS-2015-GTT01)
SPE-GC/MS Method for the Determination of 15 Pesticide Residues in Ground Water
DONG Jun,YUAN Penghui,MA Chao,GAO Shuai,WANG Qinghua,FAN Xiaojing1,2
1. Shandong Geological Engineering Investigation Institute, Jinan ,Shangdong 250014, China;2. China University of Petroleum, Beijing,State Key Laboratory of Heavy Oil Processing,Beijing 102249, China
Abstract:
The GC-MS method for the determination of 15 pesticide residues in ground water was established by utilizing the appropriate chromatographic column, further improving the chromatographic separation condition and optimizing the pretreatment method. The outstanding characteristic of this method is the fast processing speed, less solvent consumption, less environmental pollution and short running time within 25 min, which is suitable for the detection of large quantities of samples. In addition, select ion monitoring (SIM) mode combined with segmentation obtained higher sensitivity. This method has better recover and lower detection limit, the detection limit is less than 0.004 8 μg/L, and the recovery rate ranged from 85.9%~107.4%.
Key words:  Groundwater  Pesticides  GC-MS