引用本文:朱芸,李世刚,周圆,于雅东.加速溶剂萃取-气相色谱质谱法同时测定土壤及沉积物中34种有机氯农药及18种多氯联苯类化合物[J].环境监控与预警,2019,11(3):30-35
ZHU Yun,LI Shi-gang,ZHOU Yuan,YU Ya-dong.Simultaneous Determination of 34 Organochlorine Pesticides and 18 Polychlorinated Biphenyls in Soil and Sediment by Accelerated Solvent Extraction-Gas Chromatography-mass Spectrometry[J].Environmental Monitoring and Forewarning,2019,11(3):30-35
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加速溶剂萃取-气相色谱质谱法同时测定土壤及沉积物中34种有机氯农药及18种多氯联苯类化合物
朱芸,李世刚,周圆,于雅东1,2
1.云南省核工业二〇九地质大队,云南 昆明 650032;2.昆明市环境监测中心,云南 昆明 650028
摘要:
建立了加速溶剂萃取-气相色谱质谱法同时测定34 种有机氯农药(OCPs)和18种多氯联苯类化合物(PCBs)的方法。当取样量为10.0 g时,52种有机化合物的检出限为0.03~0.29 μg/kg,以空白样品为基体进行加标回收试验,平均回收率为44.7%~123.0%,相对标准偏差(RSD,n=7)为1.8%~21.5%。该方法灵敏度高,实现了低浓度有机化合物的定量分析,分析结果准确可靠,满足土壤和沉积物中34 种有机氯农药和18种多氯联苯类化合物分析的要求。
关键词:  加速溶剂萃取  土壤和沉积物  有机氯农药  多氯联苯类化合物  气相色谱质谱法
DOI:
分类号:X833;O657.7+1
文献标识码:B
基金项目:
Simultaneous Determination of 34 Organochlorine Pesticides and 18 Polychlorinated Biphenyls in Soil and Sediment by Accelerated Solvent Extraction-Gas Chromatography-mass Spectrometry
ZHU Yun,LI Shi-gang,ZHOU Yuan,YU Ya-dong1,2
1. Yunnan Nuclear Industry 209 Geological Brigade, Kunming,Yunnan 650032,China;2. Kunming Environmental Monitoring Center, Kunming,Yunnan 650028,China
Abstract:
A method for the simultaneous determination of 34 organochlorine pesticides (OCPs) and 18 polychlorinated biphenyls (PCBs) by accelerated solvent extraction-gas chromatography-mass spectrometry was established. Experiments show that the method can simultaneously determine the above 52 organic compounds. The method is simple, accurate and sensitive. When the sample size was 10.0g, the detection limits of 52 organic compounds were 0.03~0.29 μg/kg. The standard addition recovery test was carried out with blank samples as matrix. The average recovery rates were between 44.7% and 123.0%, and the relative standard deviations (RSD,n=7) were 1.8%~21.5%. The method is sensitive, accurate and reliable for quantitative analysis of low-content organic compounds, and meets the requirements for analysis of 34 organochlorine pesticides and 18 polychlorinated biphenyls in soil and sediment.
Key words:  Accelerated solvent extraction  Soil and sediment  Organochlorine pesticides  Polychlorinated biphenyls  Gas chromatography-mass spectrometry