引用本文:童彩环,秦海芝,万喜喜.离子色谱法测定土壤中草甘膦的提取溶液选择[J].环境监控与预警,2021,13(3):35-39
TONG Cai-huan, QIAN Hai-zhi, WAN Xi-xi.Selection of Extraction Solution for Determination of Glyphosate in Soil by Ion Chromatography[J].Environmental Monitoring and Forewarning,2021,13(3):35-39
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离子色谱法测定土壤中草甘膦的提取溶液选择
童彩环,秦海芝,万喜喜
作者单位
童彩环,秦海芝,万喜喜 宁波市华测检测技术有限公司浙江 宁波 315000 
摘要:
以辽宁棕壤等10种土壤为样品,探讨了水和pH值=9.00~14.00的氢氧化钠(NaOH)作为提取液对草甘膦分析的影响。结果表明,以水为提取液,仅石灰性紫色土和灰钙土能获得较高的回收率,其他所测土壤尤其是pH值<8.00的土壤其回收率较低,提取效果受土壤理化性质影响明显。以pH值=9.00~14.00的NaOH为提取液,随着提取液pH值的提高,所测土壤的回收率均随之提高,达到一定的pH值后,回收率随之提高不明显,但干扰会增多。当已知土壤相关理化性质时,可以参考回收率相关性分析选择合适的提取液。
关键词:  草甘膦  离子色谱  土壤  提取溶液
DOI:
分类号:X833;O657.7+5
文献标识码:B
基金项目:
Selection of Extraction Solution for Determination of Glyphosate in Soil by Ion Chromatography
TONG Cai-huan, QIAN Hai-zhi, WAN Xi-xi
Abstract:
10 soil samples such as Liaoning brown soil were used to explore the influence of water and NaOH with pH range of 9.00-14.00 as extraction solutions on the analysis. The results showed that only calcareous purple soil and sierozem could obtain a higher extraction rate with water as the extraction solution. Other tested soils, especially soils with pH<8, showed lower extraction rates, indicating that the extraction effect of water is affected by the physical and chemical properties of the soil. When NaOH, with pH value in the range of 9.00-14.00, was used as the extraction solution, as the pH value increased, the extraction efficiency increased. Once pH reached a certain value, the extraction efficiency would not increase significantly, but the interference would increase.Therefore, when the physical and chemical properties of the soil are available, suitable extraction solution can be selected referring to the correlation analysis of the extraction rate.
Key words:  Glyphosate  Ion chromatography  Soil  Extraction solution